p-hydroxyphenylglycine의 金屬錯體와 실리콘化合物과의 縮重合

Abstract

主鎖에 金屬이온을 가지면 일반적으로 熱的 安定性이 좋은 樹脂가 된다.

二??能性을 가진 bis-(N-(p-hydroxyphenyl)glycino)-copper(Ⅱ)를 diphenyl 및 dimethyoxysilane과 각각 p-톨루엔술폰산을 촉매로 dimethylsulfoxide(DMSO)중에서 축합시켰다.

또한 合成된 縮合物을 赤外線分光法으로 확인하였다.

Thermal stability is increased by introducing chelate ring in polymers. Polymers with chelate ring in backbone were synthesized by condensation of bis-(N-(p-hydroxyphenyl)glycino)-copper(Ⅱ) with diphenyldiethoxysilane and dimethyldiethoxysilane in dimethylsulfoxide (DMSO).

Condensation was confirmed by the infrared absorption spectrum.

Thermal stability is increased by introducing chelate ring in polymers. Polymers with chelate ring in backbone were synthesized by condensation of bis-(N-(p-hydroxyphenyl)glycino)-copper(Ⅱ) with diphenyldiethoxysilane and dimethyldiethoxysilane in dimethylsulfoxide (DMSO).

Condensation was confirmed by the infrared absorption spectrum.