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친수성기를 함유한 polysiloxane 막의 합성

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Alternative Title
Synthesis of Polysiloxane Hydrogel Membrans
Abstract
Si-H결합에 CH₂=CH-R을 부가하는 방법을 이용하여 친수성기를 함유하는 실란단량체인(2,3-epoxypropoxy)propyldiethoxymethylsilane(EDMS)과 acetoxypropyldiethoxymethylsilane(ADMS)을 합성하였다.

EDMS와 ADMS를 이용하여 poly(2,3-dihydroxypropoxy)propylmethylsiloxane과 poly(3-hydroxypropyl)methylsiloxane을 얻었다. poly(2,3-dihydroxypropoxy) propylmethylsiloxane은 42.4%의 함수율을 나타냈으며 poly(3-hydroxypropyl)methylsiloxane은 물에 용해?臼눼?.
Using the methods of addition for Si-H bond to unsaturated hydrocarbons, (2,3-epoxypropoxy)propyldiethoxymethylsilane(EDMS) and acetoxypropyldiethoxymethylsilane(ADMS) were synthesized. Poly(2,3-dihydroxypropoxy)propylmethylsiloxane and poly(3-hydroxypropy)methylsiloxane were synthesized from EDMS and ADMS, respectively. Water content of poly(2,3-dihydroxypropoxy)propylmethylsiloxane was 42.4%, and poly(3-hydroxypropyl)methylsiloxane was soluble in water.
Using the methods of addition for Si-H bond to unsaturated hydrocarbons, (2,3-epoxypropoxy)propyldiethoxymethylsilane(EDMS) and acetoxypropyldiethoxymethylsilane(ADMS) were synthesized. Poly(2,3-dihydroxypropoxy)propylmethylsiloxane and poly(3-hydroxypropy)methylsiloxane were synthesized from EDMS and ADMS, respectively. Water content of poly(2,3-dihydroxypropoxy)propylmethylsiloxane was 42.4%, and poly(3-hydroxypropyl)methylsiloxane was soluble in water.
Author(s)
윤구식
Issued Date
1987
Type
Research Laboratory
URI
https://oak.ulsan.ac.kr/handle/2021.oak/4791
http://ulsan.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000002024893
Alternative Author(s)
Yoon, Koo-Sik
Publisher
연구논문집
Language
kor
Rights
울산대학교 저작물은 저작권에 의해 보호받습니다.
Citation Volume
18
Citation Number
2
Citation Start Page
165
Citation End Page
169
Appears in Collections:
Research Laboratory > University of Ulsan Report
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